Product ID:FYROL CEF
MSDS Date:02/01/1986
FSC:8030
NIIN:00N009926
MSDS Number: BHGVN

Emergency Phone: 304-675-1150

Info Phone: 304-675-1150

Cage: 00488

Telephone: 312-906-7500

Cage: 00488

TRI(B-CHLOROETHYL)PHOSPHATE

CAS: 115-96-8

RTECS: KK2450000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 RABBIT ACUTE DERMAL >5000 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:LD50 RAT ACUTE ORAL 390 MG/KG
(FEMALE),710 MG/KG (MALE).LC50 RAT ACUTE INHALATION >5.0 MG/L.EYE
CONTACT:NON-IRRITANT TO RABBIT EYES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:N/K .SKIN:N/K .INGESTION:HARMFUL IF
SWALLOWED.MAY CAUSE IRRITATION.INHALATION:VAPOR MAY BE IRRITATING
TO RESPIRATORY TRACT & MAY CAUSE BREATHING DIFFICULTY AND PULMONARY
EDE MA.SYMPTOMS MAY BE DELAYED SEVERAL HOURS OR LONGER DEPENDING ON
EXPOSURE.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:HOLDING LIDS APART FLUSH W/ H*2O FOR @ LEAST 15 MIN.GET
MED ATTN IF IRRIT OCCURS.SKIN:REMOVE CONTAM CLTHG.IMMED FLUSH SKIN
W/ H*2O FOR @ LEAST 15 MIN.GET MED ATTN IF IRRIT
OCCURS.INGEST:IMMED GIV E LRG QUANTITIES OF H*2O.INDUCE
VOMITING.KEEP GIVING FLUIDS UNTIL VOMITUS IS CLEAR.CALL MD/POISON
CONTROL CENTER IMMED.INHAL:MOVE TO FRESH AIR.SEEK MED ATTN IMMED IF
RESP IRRIT/BRTHG DIFFICULTY OCCURS

Flash Point Method:OC
Flash Point:485F,252C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:WATER,DRY CHEMICALS,FOAM,CARBON DIOXIDE OR OTHER
SUITABLE SUFFOCATION AGENTS.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.PVNT HUM EXPOS TO SMOKE,FUMES,COMBUST PROD.EVAC NON-ESSNTL
PERS.DECONTAM BLDGS,EQUIP,ETC BEFORE RE-ENTRY/USE
Unusual Fire/Explosion Hazard:UNDER FIRE CONDITIONS.MATL MAY SUPPORT
COMBUSTION & DECOMPOSE TO GIVE OFF PHOSPHOROUS OXIDES & HCL.IT IS
SELF-EXTINGUISHING ONCE IGNITION SOURCE IS REMOVED.

Spill Release Procedures:HANDLE SMALL SPILLS ROUTINELY.USE ADEQ
VENT.WEAR RESPIRATOR & PROT CLTHG.SOAK UP POOLED LIQ W/
CLAY,SAWDUST,KITTY LITTER,FULLERS EARTH,ETC.SWEEP UP ABSORBED
MATL.PLACE IN APPROP CHEM WASTE CNTNR.SEAL & DISP OF IN APPRVD
LANDFILL.FLUSH SPILL (SEE SUP)
Neutralizing Agent:N/K

Handling and Storage Precautions:PVNT EATING,DRINKING,SMOKING,ETC IN
AREAS OF POTENTIAL EXPOS.STORE CNTNRS IN COOL DRY,WELL-VENT
AREA.USE CAUTION TO PVNT DAMAGE TO/LEAKAGE FROM CNTNRS
Other Precautions:MATL WAY SOFTEN/DETERIORATE SOME PLASTICS &
ELASTOMERS,ESP VINYL-BASED RESINS & NATL RUBBERS.CARBON STEEL IS
PREF MATL OF STORAGE.MATL MAY DECOMPOSE WHEN STORED FOR LONG
PERIODS OF TIME @ TEMP ABOVE 1 22F,50C DEPENDING ON CONDTNS &
ENVIRON.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .NECESSARY WHEN USED IN POORLY VENTILATED AREA.
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATIONS BELOW LEVELS OF CONCERN
Protective Gloves:RECOM TO PVNT CONT W/ LIQ OR AEROSOL.
Eye Protection:CHEM WORK GOGG,FACESHLD OPTIONAL .
Other Protective Equipment:SKIN CONT W/ LIQ OR ITS AEROSOL SHOULD BE
MINIMIZED THRU USE OF LONG-SLEEVED CLTHG SELECTED W/ REGARD TO
EXPOSURE LEVEL.
Work Hygienic Practices:BEFORE EATING,DRINKING OR SMOKING,HANDS AND
FACE MUST BE THOROUGHLY WASHED.
Supplemental Safety and Health
BP:293F,145C @ 0.5 MMHG.SPEC GRAV:1.42 @ 77F,25C (H*2O=1).VP:<10 TORR @
77F,25C.FIRE PT:545F,285C (COC).POUR POINT:-60F,-51C.VISCOSITY:38
CPS @ 77F,25C.SPILL PROC:AREA W/ DETERGEN & H*2O.LG SPILL:DIKE &
PUMP TO SALVAGE IAW PREDETERMINED PLAN.CONTACT SPECIALTY CHEMICAL
DIV OF STAUFFER CHEMICAL CO TO DEVELOP PLAN.

Boiling Pt:B.P. Text:SEE SUPP
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Vapor Density:N/K
Spec Gravity:SEE SUPP DATA
Evaporation Rate & Reference:N/K
Solubility in Water:<1% AT 77F,25C
Appearance and Odor:CLEAR,COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
THIS MATERIAL WILL HYDROLIZE SLOWLY UNDER WET ALKALINE OR ACIDIC
CONDITIONS.
Stability Condition to Avoid:THIS MATERIAL IS THERMALLY STABLE AT
TEMPERATURES BELOW 302F,150C.ABOVE THIS TEMPERATURE,ACIDS WILL
FORM.
Hazardous Decomposition Products:PHOSPHORUS OXIDES AND HYDROGEN
CHLORIDE.

Waste Disposal Methods:DISP MUST BE IAW FED,STATE & LOC REGS .MATL THAT
CANNOT BE USED OR CHEM REPROCESSED SHOULD BE DISP OF IN APPRVD
LANDFILL OR IN WAY THAT WILL NOT HARM ENVIRON.UNUSED MATL CAN BE
INCIN BY MEANS WH ICH PROVIDE APPROP ENVIRON POLLUTION CONTROLS.

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